Researchers from NOAA and the University of Colorado have devised a breakthrough method for estimating national emissions of carbon dioxide from fossil fuels using ambient air samples and a well-known isotope of carbon scientists have relied on for decades to date archaeological sites. In a paper published in Proceedings of the National Academy of Sciences, they report the first-ever national scale estimate of fossil-fuel derived carbon dioxide (CO2) emissions obtained by observing CO2 and its naturally occurring radioisotope, carbon-14, from air samples collected by NOAA’s Global Greenhouse Gas Reference Network.