Publications

Publications from the last 5 years

Bold and italicized authors indicate former/current group members

Full list of Publications/Conference Presentations can be found at Adam's Google Scholar. 

2024

  1. Yang, Y.; Yuwono, J. A.; Whittaker, T.; Ibáñez, M. M.; Wang, B.; Kim, C.; Borisevich, A. Y.; Chua, S.; Prada, J. P.; Wang, X.; Autran, P.-O.; Unocic, R. R.; Dai, L.; Holewinski, A.; Bedford, N. M. Double Hydroxide Nanocatalysts for Urea Electrooxidation Engineered toward Environmentally Benign Products. Advanced Materials2024, 36 (35), 2403187. DOI: 10.1002/adma.202403187.

  2. Whittaker, T. N.; Fishler, Y.; Clary, J. M.; Brimley, P.; Holewinski, A.; Musgrave, C. B.; Farberow, C. A.; Smith, W. A.; Vigil-Fowler, D. Insights into Electrochemical CO2 Reduction on Metallic and Oxidized Tin Using Grand-Canonical DFT and In Situ ATR-SEIRA Spectroscopy. ACS Catal.2024, 14 (11), 8353–8365. DOI: 10.1021/acscatal.4c01290.

    cartoon representing reduction of CO2 to formate on tin and tin oxide

  3. Tian, C.; Dorakhan, R.; Wicks, J.; Chen, Z.; Choi, K.-S.; Singh, N.; Schaidle, J. A.; Holewinski, A.; Vojvodic, A.; Vlachos, D. G. Progress and Roadmap for Electro-Privileged Transformations of Bio-Derived Molecules. Nature Catalysis2024, 1–11. DOI: 10.1038/s41929-024-01131-6.

  4. Fishler, Y.; Leick, N.; Teeter, G.; Holewinski, A.; Smith, W. A. Layered Sn–Au Thin Films for Increased Electrochemical ATR-SEIRAS Enhancement. ACS Appl. Mater. Interfaces2024, 16 (15), 19780–19791. DOI: 10.1021/acsami.4c01525.

  5. Ramos, N. C.; Holewinski, A. Recent Advances in Anodic Hydrogen Production: Electrochemical Oxidative Dehydrogenation of Aldehydes to Carboxylates. Current Opinion in Electrochemistry2024, 45, 101484. DOI: 10.1016/j.coelec.2024.101484.

2023

  1. Hasse, J. C.; Manyé Ibáñez, M.; Holewinski, A. Impact of Electrolyte Composition on Bulk Electrolysis of Furfural over Platinum Electrodes**. ChemCatChem2023, 15 (23), e202300988. DOI: 10.1002/cctc.202300988.

  2. Ramos, N. C.; Manyé Ibáñez, M.; Mittal, R.; Janik, M. J.; Holewinski, A. Combining Renewable Electricity and Renewable Carbon: Understanding Reaction Mechanisms of Biomass-Derived Furanic Compounds for Design of Catalytic Nanomaterials. Acc. Chem. Res.2023, 56 (19), 2631–2641. DOI: 10.1021/acs.accounts.3c00368.

    pictorial abstract representing methods used to study reaction mechanisms of furanic compoundss

  3. Lucas, F. W. S.; Ramos, N. C.; Schwartz, D. K.; Medlin, J. W.; Holewinski, A. Understanding Reactivity of Self-Assembled Monolayer-Coated Electrodes: SAM-Induced Surface Reconstruction. Electrochimica Acta2023, 459, 142586. DOI: 10.1016/j.electacta.2023.142586.

  4. Holewinski, A. Hydride Transfer Gets a Recharge. Nat Catal2023, 6 (4), 296–297. DOI: 10.1038/s41929-023-00946-z.

  5. Al Khulaifi, F. M.; Alsunni, Y. A.; Musgrave, C. B.; Holewinski, A.; Medlin, J. W. Impact of Pretreatment and Thiol Modifiers on the Partial Oxidation of Glutaraldehyde Using Pd/Al2O3. Applied Catalysis A: General2023, 661, 119229. DOI: 10.1016/j.apcata.2023.119229.

  6. Ramos, N. C.; Medlin, J. W.; Holewinski, A. Electrochemical Stability of Thiolate Self-Assembled Monolayers on Au, Pt, and Cu. ACS Appl. Mater. Interfaces2023, 15 (11), 14470–14480. DOI: 10.1021/acsami.3c01224.

2022

  1. Delluva, A. A.; Kulberg-Savercool, J.; Holewinski, A. Thermal Enhancement of Product Conductivity Raises Capacity in Solid-State Li-O2 Batteries. ACS Appl. Energy Mater.2022, 5 (12), 14739–14747. DOI: 10.1021/acsaem.2c02071.

  2. Baz, A.; Lyons, M.; Holewinski, A. Dynamic Electrocatalysis: Examining Resonant Catalytic Rate Enhancement under Oscillating Electrochemical Potential. Chem Catalysis2022, 2 (12), 3497–3516. DOI: 10.1016/j.checat.2022.09.002.

  3. Hasse, J. C.; Agrawal, N.; Janik, M. J.; Holewinski, A. ATR-SEIRAS Investigation of the Electro-Oxidation Mechanism of Biomass-Derived C5 Furanics on Platinum Electrodes. J. Phys. Chem. C2022, 126 (16), 7054–7065. DOI: 10.1021/acs.jpcc.2c01259.

2021

  1. S. Lucas, F. W.; Fishler, Y.; Holewinski, A. Tuning the Selectivity of Electrochemical Levulinic Acid Reduction to 4-Hydroxyvaleric Acid: A Monomer for Biocompatible and Biodegradable Plastics. Green Chemistry2021, 23 (22), 9154–9164. DOI: 10.1039/D1GC02826J.

  2. Baz, A.; Dix, S. T.; Holewinski, A.; Linic, S. Microkinetic Modeling in Electrocatalysis: Applications, Limitations, and Recommendations for Reliable Mechanistic Insights. Journal of Catalysis2021, 404, 864–872. DOI: 10.1016/j.jcat.2021.08.043.

  3. Spivey, T. D.; Holewinski, A. Selective Interactions between Free-Atom-like d-States in Single-Atom Alloy Catalysts and Near-Frontier Molecular Orbitals. J. Am. Chem. Soc.2021, 143 (31), 11897–11902. DOI: 10.1021/jacs.1c04234.

    Pictorial abstract of selective interactions between single atom alloy catalysts and frontier orbitals of adsorbing species

  4. Delluva, A. A.; Kulberg-Savercool, J.; Holewinski, A. Decomposition of Trace Li2CO3 During Charging Leads to Cathode Interface Degradation with the Solid Electrolyte LLZO. Advanced Functional Materials2021, 31 (34), 2103716. DOI: 10.1002/adfm.202103716.

  5. Baz, A.; Holewinski, A. Predicting Macro-Kinetic Observables in Electrocatalysis Using the Generalized Degree of Rate Control. Journal of Catalysis2021, 397, 233–244. DOI: 10.1016/j.jcat.2021.03.014.

  6. Lei, Z.; Lucas, F. W. S.; Canales Moya, E.; Huang, S.; Rong, Y.; Wesche, A.; Li, P.; Bodkin, L.; Jin, Y.; Holewinski, A.; Zhang, W. Highly Stable Dioxin-Linked Metallophthalocyanine Covalent Organic Frameworks. Chinese Chemical Letters2021, 32 (12), 3799–3802. DOI: 10.1016/j.cclet.2021.04.047.

  7. Lucas, F. W. S.; Grim, R. G.; Tacey, S. A.; Downes, C. A.; Hasse, J.; Roman, A. M.; Farberow, C. A.; Schaidle, J. A.; Holewinski, A. Electrochemical Routes for the Valorization of Biomass-Derived Feedstocks: From Chemistry to Application. ACS Energy Lett.2021, 6 (4), 1205–1270. DOI: 10.1021/acsenergylett.0c02692.

  8. Harris, A. W.; Roy, S.; Ganguly, S.; Parameswar, A. V.; Lucas, F. W. S.; Holewinski, A.; Goodwin, A. P.; Cha, J. N. Investigating the Use of Conducting Oligomers and Redox Molecules in CdS–MoFeP Biohybrids. Nanoscale Advances2021, 3 (5), 1392–1396. DOI: 10.1039/D0NA00678E.

2020

  1. Román, A. M.; Spivey, T. D.; Medlin, J. W.; Holewinski, A. Accelerating Electro-Oxidation Turnover Rates via Potential-Modulated Stimulation of Electrocatalytic Activity. Ind. Eng. Chem. Res.2020, 59 (45), 19999–20010. DOI: 10.1021/acs.iecr.0c04414.

  2. Román, A. M.; Agrawal, N.; Hasse, J. C.; Janik, M. J.; Medlin, J. W.; Holewinski, A. Electro-Oxidation of Furfural on Gold Is Limited by Furoate Self-Assembly. Journal of Catalysis2020, 391, 327–335. DOI: 10.1016/j.jcat.2020.08.034.

  3. Delluva, A. A.; Dudoff, J.; Teeter, G.; Holewinski, A. Cathode Interface Compatibility of Amorphous LiMn2O4 (LMO) and Li7La3Zr2O12 (LLZO) Characterized with Thin-Film Solid-State Electrochemical Cells. ACS Appl. Mater. Interfaces2020, 12 (22), 24992–24999. DOI: 10.1021/acsami.0c03519.

  4. Barton, Z. J.; Garrett, G. H.; Kurtyka, N.; Spivey, T. D.; Schaidle, J. A.; Holewinski, A. Electrochemical Reduction Selectivity of Crotonaldehyde on Copper. J Appl Electrochem2021, 51 (1), 5–17. DOI: 10.1007/s10800-020-01415-2.

  5. Baz, A.; Holewinski, A. Understanding the Interplay of Bifunctional and Electronic Effects: Microkinetic Modeling of the CO Electro-Oxidation Reaction. Journal of Catalysis2020, 384, 1–13. DOI: 10.1016/j.jcat.2020.02.003.

    Pictorial abstract representing the bifunctional and electronic effects of alloying on CO oxidation

2019

  1. Mark, L. O.; Agrawal, N.; Román, A. M.; Holewinski, A.; Janik, M. J.; Medlin, J. W. Insight into the Oxidation Mechanism of Furanic Compounds on Pt(111). ACS Catal.2019, 9 (12), 11360–11370. DOI: 10.1021/acscatal.9b03983.

  2. Román, A. M.; Hasse, J. C.; Medlin, J. W.; Holewinski, A. Elucidating Acidic Electro-Oxidation Pathways of Furfural on Platinum. ACS Catal.2019, 9 (11), 10305–10316. DOI: 10.1021/acscatal.9b02656.

    mechanism and products of furfural oxidation in acidic media

  3. Agrawal, N.; Gong, L.; Roman, A.; Mark, L.; Medlin, W.; Holewinski, A.; Janik, M. J. Mechanistic Investigations for Electrocatalytic Oxidation of Furfural Using Density Functional Theory. Meet. Abstr.2019, MA2019-02 (20), 1030. DOI: 10.1149/MA2019-02/20/1030.

  4. Gong, L.; Agrawal, N.; Roman, A.; Holewinski, A.; Janik, M. J. Density Functional Theory Study of Furfural Electrochemical Oxidation on the Pt (1 1 1) Surface. Journal of Catalysis2019, 373, 322–335. DOI: 10.1016/j.jcat.2019.04.012.