Titanium-Anthraquinone Material as a New Design Approach for Electrodes in Aqueous Rechargeable Batteries
The need for expanded energy storage motivates material development for scalable aqueous secondary batteries. The combination of transition metals with redox-active organics represents a new approach to functional material design. Here, we detail the synthesis of titanium(IV) 1,8-dihydroxyanthraquinone (Ti(1,8-DHAQ)2) as a novel redox-active material and demonstrate its use as a negative electrode in an aqueous battery. This one-pot synthesis results in amorphous micron-scale particles with titanium binding directly to the carbonyl feature as evidenced by scanning electron microscopy and infrared spectroscopy. When assembled in a coin cell with a lithium manganese oxide positive electrode, the active material can be electrochemically cycled with a charge density of 40 mAh/g at 1.1 V. This represents a new method of creating simple and scalable electrodes using metal-organic materials for versatile energy storage applications.