2015

Electron transfer from photoexcited CdS nanorods to [FeFe]-hydrogenase is a critical step in photochemical H2 production by CdS–hydrogenase complexes. By accounting for the distributions in the numbers of electron traps and enzymes adsorbed, we

In molecular crystals that exhibit singlet fission, quantum yields depend strongly on intermolecular configurations that control the relevant electronic couplings. Here, we explore how noncovalent interactions between molecules and surfaces

Single-molecule studies probing the end-to-end extension of long DNAs have established that the mechanical properties of DNA are well described by a wormlike chain force law, a polymer model where persistence length is the only adjustable parameter

We present a model to describe collective features of singlet fission in molecular crystals and analyze it using many-body theory. The model we develop allows excitonic states to delocalize over several chromophores which is consistent with the

Vibrational spectroscopy can provide information about structure, coupling, and dynamics underlying the properties of complex molecular systems. While measurements of spectral line broadening can probe local chemical environments, the spatial