OVERVIEW of WASTEWATER TREATMENT
Discharge Standards for Municipal Wastewater:
Conventional:
BOD = biochemical oxygen demand; measure of organic content
TSS = total suspended solids
Oil and grease
pH - ciritical if nitrified-ww
Nonconventional:
NH3-H = ammonia-nitrogen; represents a nitrogenous oxygen demand; std < 1 to 4 mg/L
P = phosphorus
NO3 + NO2 = nitrate+nitrite
TDS = total dissolved solids
fecal coliform - bacteria
COD, Cr+6, Organic-N, phenols, TOC, fluoride, manganese, pesticide active ingred.
Actual concentration limits are set by the NPDES permit, negotiated with the state. These should be provided by the Colorado Dept. of Public Health in Sept. Although there are no current limits on annonia, N, or P, it is anticipated that these limits will be added, requiring tertiary treatment for nutrient removal at the plant. Common limits in Europe are: 20 mg/L BOD5, 30 mg/L suspended solids; COD <125 mg/L, Total P = 1 mg/L, Total N = 10 mg/L
Important Reactions:
Theoretical Oxygen demand (ThOH) = amount of oxygen to convert substance to CO2, H2O
Chemical oxygen demand (COD) = experimentally measured oxidation with dichromate; close to ThOD, but pyridines, ammonia, purines are not oxidized
Biochemical oxygen demand (BOD) = amount of oxygen consumed by bacteria during compound degradation; BOD < ThOD due to C incorporated into biomass
influent municipal WW COD:BOD5 2-2.5; effluent sBOD5 2-3 mg/L, sCOD 40-60 mg/L
Nitrogenous oxygen demand: NH4+ + 2 O2 -> NO3- + H2O + 2 H+
Denitrification by bacteria (in absence of oxygen): nitrate -> nitrite -> N2 (g)
Anaerobic bacterial degradation of organics -> CO2 + CH4 + water (NH3, H2S, mercaptans)
Phosphorus: stored intracellularly in polyphosphate, uptake in aerobic phase
Unit Operations:
Pretreatment: bar racks, grit chambers, communitors, flow equalization
Primary treatment: primary sedimentation tanks
Secondary Treatment (for carbon removal):
Disinfection
Advanced WW Treatment (AWT) or Tertiary Treatment (for N, P, toxics removal)
filtration, carbon adsorption, phosphorus removal, nitrogen control, land treatment
Residuals handling: sludge